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Low-density and low-temperature gas is overheated with the _shielded tables, which is also very odd because shielding is not expected to have any effect in this regime. There is no issue with the Cloudy tables that do not include shielding.
As an example of what kind of impact this can have, I am showing here the evolution of gas temperature at mean cosmic density as a function of redshift for a cosmological simulation that only includes gas cooling (no star formation, no feedback). It is clear that the shielded tables overheat this low-density gas.
Thanks to Volker Springel, Yves Revaz, and Matthew Smith for discovering and investigating this problem.